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Words near each other
・ Chirakkalkulam
・ Chirakkara
・ Chirakodinja Kinavukal
・ Chirakumar Sabha
・ Chiral algebra
・ Chiral anomaly
・ Chiral auxiliary
・ Chiral color
・ Chiral column chromatography
・ Chiral derivatizing agent
・ Chiral gauge theory
・ Chiral homology
・ Chiral knot
・ Chiral Lewis acid
・ Chiral Lie algebra
Chiral ligand
・ Chiral model
・ Chiral perturbation theory
・ Chiral Photonics
・ Chiral polytope
・ Chiral pool synthesis
・ Chiral Potts curve
・ Chiral Potts model
・ Chiral resolution
・ Chiral superfield
・ Chiral symmetry breaking
・ Chirala
・ Chirala (Assembly constituency)
・ Chirala mandal
・ Chirala railway station


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Chiral ligand : ウィキペディア英語版
Chiral ligand
In chemistry a chiral ligand is a specially adapted ligand used for asymmetric synthesis. This ligand is an enantiopure organic compound that combines with a metal center by chelation to form an asymmetric catalyst. This catalyst engages in a chemical reaction and transfers its chirality to the reaction product which as a result also becomes chiral. In an ideal reaction one equivalent of catalyst can turn over many more equivalents of reactant which enables the synthesis of a large amount of a chiral compound from achiral precursors with the aid of a very small (often expensive) chiral ligand.
==First discovery==
The first such ligand, the diphosphine DiPAMP was developed in 1968 by William S. Knowles of Monsanto Company, who won the 2001 Nobel Prize in Chemistry,〔Nobel prize 2001 www.nobelprize.org (Link )〕 and ultimately used in the industrial production of L-DOPA.
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抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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